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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1982 Volume 51, Issue 10, Pages 1733–1752 (Mi rcr3426)

This article is cited in 18 papers

Phase Structure of Epoxide–Rubber Systems

V. P. Volkovab, G. F. Roginskayaab, A. E. Chalykhab, B. A. Rozenbergab

a Institute of Physical Chemistry, the USSR Academy of Sciences, Moscow
b Chernogolovka Institute of Chemical Physics of the USSR Academy of Sciences

Abstract: Formation of the phase structure during three-dimensional polycondensation in heterophase epoxide–rubber systems is discussed. Aspects of the phase equilibrium and the interdiffusion of the components in the initial systems and during the chemical reaction are examined. A two-stage mechanism of structure formation is suggested. A relation is demonstrated between the thermodynamic affinity of the components and the final phase structure. Possible methods for obtaining systems having specified parameters are considered. A list of 102 references is included.

UDC: 541.64:536.7

DOI: 10.1070/RC1982v051n10ABEH002936


 English version:
Russian Chemical Reviews, 1982, 51:10, 994–1006

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