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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1984 Volume 53, Issue 4, Pages 545–565 (Mi rcr3543)

This article is cited in 24 papers

A Microheterogeneous Medium for Chemical (Enzymic) Reactions Based on a Colloidal Solution of Water in an Organic Solvent

Yu. L. Khmel'nitskii, A. V. Levashov, N. L. Klyachko, K. Martinek

M. V. Lomonosov Moscow State University, Department of Chemistry

Abstract: The structure and properties of inverted surfactant micelles in non-polar solvents are examined. The methods for the solubilisation of proteins (enzymes) in such systems and the molecular mechanisms of solubilisation are characterised. The kinetics of chemical enzymic reactions in inverted micelle systems are discussed. The factors influencing the catalytic activity and substrate specificity of the solubilised enzymes are analysed. The characteristic features of the shift of the chemical equilibrium in inverted micelle systems are considered and the prospects for the employment of such systems in fundamental research (particularly in the modelling of the structure and functions of biological membranes) and for the solution of applied problems in chemistry are discussed.
The bibliography includes 132 references.

UDC: 661.185.1+547.96+541.128.135+542.98

DOI: 10.1070/RC1984v053n04ABEH003052


 English version:
Russian Chemical Reviews, 1984, 53:4, 319–331

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© Steklov Math. Inst. of RAS, 2024