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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1984 Volume 53, Issue 10, Pages 1601–1624 (Mi rcr3583)

This article is cited in 1 paper

The Temperature Jump Method and Its Application in the Study of Complex Formation

V. I. Pogonin, A. K. Chibisov

Institute of Geochemistry and Analytic Chemistry, Academy of Sciences of the USSR

Abstract: The present state of the apparatus used in the temperature jump method (methods for rapid heating, recording concentration changes, and collecting and processing experimental data) has been described. The formal kinetics of chemical relaxation on complex formation (relaxation times and amplitudes) have been examined. The mechanisms of complex formation by metal ions with various ligands, based on data obtained by the temperature jump method, have been discussed.
The bibliography contains 118 references.

UDC: 541.12.036+541.49

DOI: 10.1070/RC1984v053n10ABEH003132


 English version:
Russian Chemical Reviews, 1984, 53:10, 929–942

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