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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1985 Volume 54, Issue 7, Pages 1057–1099 (Mi rcr3644)

This article is cited in 11 papers

Reactions in Organic Crystals

V. E. Shklover, T. V. Timofeeva

A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow

Abstract: Structural investigations of two types of chemical reactions occurring in organic crystals on heating and irradiation are examined, namely intermolecular rearrangements (including the rearrangement of molecules via the transfer of individual atoms and groups of atoms, isomerisation, stereo-isomerisation, etc.) and reactions with elimination of small molecules (N2, CO2, H2O, HHal). Solid-phase processes are discussed in terms of topochemical reactions and reactions in non-crystalline (amorphous) regions.
The bibliography includes 195 references.

UDC: 541.64+541.17

DOI: 10.1070/RC1985v054n07ABEH003097


 English version:
Russian Chemical Reviews, 1985, 54:7, 619–644

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