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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1985 Volume 54, Issue 10, Pages 1674–1705 (Mi rcr3670)

This article is cited in 25 papers

Advances in the Development of Methods for the Epoxidation of Olefins

V. G. Dryuk

Dnepropetrovsk State University, Department of Chemistry

Abstract: Data obtained in recent years on the epoxidising agents and the mechanism of their interaction with olefins are surveyed. Different types of hydroperoxides as well as certain short-lived epoxidising intermediates of the molecular and radical types functioning in situ are examined.
The results of the stereospecific epoxidation of aliphatic and alicyclic compounds using the directing influence of functional groups (OH, COOH, R, SiR3, etc.) are presented.
The bibliography includes 225 references.

UDC: 547.422.127

DOI: 10.1070/RC1985v054n10ABEH003153


 English version:
Russian Chemical Reviews, 1985, 54:10, 986–1005

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