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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1986 Volume 55, Issue 1, Pages 29–61 (Mi rcr3686)

This article is cited in 5 papers

The Structure of the Active Centres and Stereoregulation in the Ionic–Coordination Polymerisation of α-Alkenes and 1,3-Dienes on Ziegler–Natta Catalysts

K. S. Minskera, M. M. Karpasasa, G. E. Zaikovb

a Bashkir State University, Ufa
b Institute of Chemical Physics of the USSR Academy of Sciences, Moscow

Abstract: The development of theories of the mechanism of the stereospecific polymerisation of α-alkenes and dienes on Ziegler–Natta catalysts has been examined. Theories of the formation and structure of the active centres, the role of the heterogeneous component of the catalyst, the mechanism of chain initiation and growth, and the mechanism of stereoregulation in the polymerisation of alkenes and dienes have been discussed.
The bibliography contains 115 references.

UDC: 541.64; 678-1

DOI: 10.1070/RC1986v055n01ABEH003169


 English version:
Russian Chemical Reviews, 1986, 55:1, 17–38

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