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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1986 Volume 55, Issue 7, Pages 1147–1161 (Mi rcr3730)

This article is cited in 3 papers

The Physical Chemistry of the Intramolecular Cyclodehydration Reactions of Prepolymers

I. B. Rabinovicha, N. V. Karyakina, A. L. Rusanovb, V. V. Korshakb

a Gor'kii State University
b A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow

Abstract: The experimental data on the thermodynamics of the intramolecular cyclodehydration reactions of prepolymers in the solid phase are examined and treated systematically. The changes in the thermodynamic functions of the above processes have been analysed in detail over a wide temperature range. The temperature ranges corresponding to the formation of polyheteroarylenes which are "defect-free" to the maximum extent have been estimated.
The bibliography includes 65 references.

UDC: 547:64

DOI: 10.1070/RC1986v055n07ABEH003213


 English version:
Russian Chemical Reviews, 1986, 55:7, 637–646

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