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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1986 Volume 55, Issue 8, Pages 1258–1281 (Mi rcr3734)

This article is cited in 2 papers

The Present State and Problems of the Theory of the Kinetics of Electrode Reactions Accompanied by the Adsorption of Inactive Substances and Reagents

V. S. Krylovab, B. B. Damaskinab, V. A. Kir'yanovab

a M. V. Lomonosov Moscow State University
b Frumkin Institute of Electrochemistry of the USSR Academy of Sciences, Moscow

Abstract: Problems in the theoretical description of the influence of the adsorption of dissolved species on the rates of electrode processes have been discussed. Present-day theories of the mechanism of the interaction between adsorbed species and ionic reagents have been used to develop a general statistical-mechanical approach to the quantitative examination of the macrokinetics of heterogeneous transformations complicated by the adsorption of ionic or dipolar components of the solution, including the adsorption of the reagents themselves.
The bibliography contains 84 references.

UDC: 541.138

DOI: 10.1070/RC1986v055n08ABEH003217


 English version:
Russian Chemical Reviews, 1986, 55:8, 706–720

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