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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1987 Volume 56, Issue 3, Pages 447–465 (Mi rcr3786)

This article is cited in 19 papers

Application of the Spin Trapping Method in Kinetic Measurements

R. G. Gasanov, R. Kh. Freidlina

A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow

Abstract: The results obtained in recent years by the spin trapping method in the solution of a number of kinetic problems are analysed and a systematic account is given of the rate constants for the addition of alkyl, polychloroalkyl and hetero-radicals as well as certain others to nitroso-compounds and nitrones; the kinetic data obtained by the spin trapping method in the study of the isomerisation, fragmentation, elimination, substitution and addition reactions are surveyed.
The bibliography includes 127 references.

UDC: 541.127:541.515

DOI: 10.1070/RC1987v056n03ABEH003269


 English version:
Russian Chemical Reviews, 1987, 56:3, 264–274

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