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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1987 Volume 56, Issue 5, Pages 754–792 (Mi rcr3799)

This article is cited in 109 papers

Activation and Catalytic Reactions of Alkanes in Solutions of Metal Complexes

A. E. Shilov, G. B. Shul'pin

Institute of Chemical Physics of the USSR Academy of Sciences, Moscow

Abstract: The reactions of saturated hydrocarbons and compounds modelling them with metal complexes, leading to the cleavage of the C–H and C–C bonds, are examined. In particular, processes which result in the formation of organometallic derivatives are described and the mechanism of the oxidation of alkanes by enzymes and their chemical models is discussed.
The bibliography includes 355 references.

UDC: 541.127

DOI: 10.1070/RC1987v056n05ABEH003282


 English version:
Russian Chemical Reviews, 1987, 56:5, 442–464

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