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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1988 Volume 57, Issue 8, Pages 1353–1402 (Mi rcr3907)

This article is cited in 25 papers

The Synthesis and Complex Forming Capacity of Phosphorus-containing Macrocycles

E. N. Tsvetkov, A. N. Bovin, V. Kh. Syundyukova

Institute of Physiologically Active Compounds of the USSR Academy of Sciences, Chernogolovka

Abstract: The review considers questions concerning the synthesis and complex-forming capacity of macrocyclic compounds containing in the ring phosphorus atoms with different degrees of coordination (from three to five) as well as macroheterocycles with phosphorus-containing side chains (lariat compounds). The introduction of the phosphoryl group into the macrocycle lowers the stability of the complexes of the macrocyclic compounds with alkali metals and reduces the selectivity compared with the analogous crown-ethers. Only the lithium cation in the case of macrocyclic phosphine oxides is an exception. Lariat macrocycles are promising: the phosphorus fragment ensures the effective additional binding of the cation imparting a high stability to the complex.
The bibliography includes 191 references.

UDC: 547.89

DOI: 10.1070/RC1988v057n08ABEH003390


 English version:
Russian Chemical Reviews, 1988, 57:8, 776–800

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