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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1989 Volume 58, Issue 7, Pages 1091–1104 (Mi rcr3984)

This article is cited in 5 papers

Spectroscopic study of carbenes in low-temperature matrices

P. S. Zuev, O. M. Nefedov

N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow

Abstract: The review surveys and gives a systematic account of the literature data on the IR and UV spectroscopic studies on carbenes in low-temperature matrices. The methods of generation and isolation of carbenes in inert matrices at temperatures around 10 K are examined. The possibility of applying the data obtained to the study of the structure of carbenes and to the determination of the mechanisms of reactions involving them is demonstrated.
The bibliography includes 67 references.

UDC: 543.422.4:541.144.8

DOI: 10.1070/RC1989v058n07ABEH003466


 English version:
Russian Chemical Reviews, 1989, 58:7, 636–643

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