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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1989 Volume 58, Issue 11, Pages 1844–1868 (Mi rcr4014)

This article is cited in 8 papers

Reactions involving the addition of N-halogenoamides to unsaturated compounds

N. N. Labeish, A. A. Petrov

Leningrad Technological Institute

Abstract: The literature data on the reactions involving the addition of N-halogeno- and NN-dihalogeno-amides of carboxylic sulphonic, sulphuric, and phosphoric acids as well as the esters of N-halogeno- and NN-dihalogeno-carbamic acids to various types of unsaturated compounds are surveyed. In many cases, the addition takes place with a different regiospecificity than for other compounds with N-halogen bonds, which has been explained by differences between the reaction mechanisms. The adducts of halogeno-amides with unsaturated compounds can be used in organic synthesis, especially in the synthesis of amides, aziridines, and other heterocyclic compounds.
The bibliography includes 113 references.

UDC: 547.316.4+547.495.1+541.52

DOI: 10.1070/RC1989v058n11ABEH003496


 English version:
Russian Chemical Reviews, 1989, 58:11, 1048–1061

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