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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1989 Volume 58, Issue 12, Pages 1945–1970 (Mi rcr4017)

This article is cited in 10 papers

The development of the concept of the chemical bond from hydrogen to cluster compounds

N. P. Gambaryan, I. V. Stankevich

A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow

Abstract: The principal types of chemical bond have been analysed, and their ranges of applicability noted. Fields in which the concept of a localised bond is inapplicable have been indicated, and, in particular, the electronic structure of Δ-polyhedral clusters has been examined. The principle of isolobal analogy has been discussed, and its unique importance for an understanding of the structure of organometallic compounds has been demonstrated.
The bibliography contains 136 references.

UDC: 541.67:541.142

DOI: 10.1070/RC1989v058n12ABEH003499


 English version:
Russian Chemical Reviews, 1989, 58:12, 1103–1118

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