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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2016 Volume 85, Issue 3, Pages 248–279 (Mi rcr4098)

This article is cited in 94 papers

Photocatalytic activity of layered perovskite-like oxides in practically valuable chemical reactions

I. A. Rodionov, I. A. Zvereva

Saint Petersburg State University

Abstract: The photocatalytic properties of layered perovskite-like oxides corresponding to the Ruddlesen–Popper, Dion–Jacobson and Aurivillius phases are considered. Of the photocatalytic reactions, the focus is on the reactions of water splitting, hydrogen evolution from aqueous solutions of organic substances and degradation of model organic pollutants. Possibilities to conduct these reactions under UV and visible light in the presence of layered perovskite-like oxides and composite photocatalysts based on them are shown. The specific surface area, band gap energy, particle morphology, cation and anion doping and surface modification are considered as factors that affect the photocatalytic activity. Special attention is paid to the possibilities to enhance the photocatalytic activity by intercalation, ion exchange and exfoliation, which are inherent in this class of compounds. Conclusions are made about the prospects for the use of layered perovskite-like oxides in photocatalysis.
The bibliography includes 253 references.

Received: 03.12.2014

DOI: 10.1070/RCR4547


 English version:
Russian Chemical Reviews, 2016, 85:3, 248–279

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