RUS  ENG
Full version
JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2016 Volume 85, Issue 11, Pages 1215–1228 (Mi rcr4138)

This article is cited in 17 papers

New approaches to the synthesis of transition-metal complexes of fullerenes $\mathrm C_{60}$ and $\mathrm C_{70}$

D. V. Konarev, R. N. Lyubovskay

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region

Abstract: The most important fields of coordination chemistry of fullerenes, including those dealing with synthesis and properties of $\eta^{2}$ complexes, multinuclear complexes and coordination dimers, have been considered. In addition, our recent results have been presented concerning the synthesis of fullerene complexes with transition metals by the reduction method and through the reaction of transition-metal compounds with fullerene radical anion salts. The properties of coordination compounds with monomeric, dimeric and polymeric fullerenes as well as with fullerene anions are discussed.
The bibliography includes 103 references.

Keywords: Fullerenes C<sub>60</sub> and C<sub>70</sub>, coordination compounds, transition metals, reduction, magnetic properties EPR spectroscopy, spectra in the IR- and UV-visible-near IR-ranges.

Received: 27.03.2016

DOI: 10.1070/RCR4645


 English version:
Russian Chemical Reviews, 2016, 85:11, 1215–1228

Bibliographic databases:


© Steklov Math. Inst. of RAS, 2024