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Usp. Khim., 2020 Volume 89, Issue 1, Pages 55–124 (Mi rcr4278)

This article is cited in 136 papers

Progress in the chemistry of nitrogen-, oxygen- and sulfur-containing heterocyclic systems

N. N. Makhova, L. I. Belen'kii, G. A. Gazieva, I. L. Dalinger, L. S. Konstantinova, V. V. Kuznetsov, A. N. Kravchenko, M. M. Krayushkin, O. A. Rakitin, A. M. Starosotnikov, L. L. Fershtat, S. A. Shevelev, V. Z. Shirinian, V. N. Yarovenko

N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Abstract: The review is devoted to modern trends in the chemistry of nitrogen-, oxygen- and sulfur-containing monocyclic, polynuclear and benzo(hetero)annulated heterocyclic compounds. Methods for the synthesis and chemical reactivity of furazan, furoxan, thiazole, thiadiazole, dithiazole, thiophene, glycoluril, imidazotriazine, diaziridine and other heterocycles are discussed. Characteristic features of reactions depending on the structure of the starting compounds, intermediates and reaction medium (organic solvents, ionic liquids) and mechanistic aspects of the most interesting transformations are considered. Data on the biological activities and prospects for practical applications of the indicated heterocyclic systems are presented.
The bibliography includes 383 references.

Keywords: furazans, furoxans, thiazoles, thiadiazoles, dithiazoles, thiophenes, glycolurils, imidazotriazines, spiropyrrolidineoxindoles, diaziridines, azometine imines, photoactive compounds, spiropyranes, spirooxazines, merocyanine dyes, photochrom dihetaryletenes, дигетарилэтены, fulgides, fulgimides, chromones, cyc;oaddition, rearrangements, pharmacologically activity.

Received: 01.08.2019

DOI: 10.1070/RCR4914


 English version:
Russian Chemical Reviews, 2020, 89:1, 55–124

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