Binary mixtures of semicrystalline polymers with low-molecular-mass compounds: thermal behaviour and phase structure

The results of phase equilibrium studies in mixtures of semicrystalline polymers with low-molecular-mass compounds are summarized and analyzed. A new classification of phase diagrams for such mixtures is proposed. Alternative points of view on the phase composition of semicrystalline polymers are presented. The phase structure evolution during the thermally induced phase separation of mixtures is monitored and the morphology of the forming capillary porous bodies as precursors of polymeric membranes is described. The general regularities concerning the influence of the nature of mixture components, polymer molecular mass, temperature scanning rate and other factors on the topology of phase diagrams are considered. Experimental methods used to construct the phase diagrams of mixtures and to study features of their phase structure are compared.
The bibliography includes 203 references.