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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2020 Volume 89, Issue 9, Pages 966–998 (Mi rcr4309)

This article is cited in 27 papers

Mono- and binuclear complexes of group 5 metals with diimine ligands: synthesis, reactivity and prospects for application

I. S. Fomenko, A. L. Gushchin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk

Abstract: Published data on the coordination compounds of group 5 metals with diimine type ligands are surveyed. Methods of synthesis, structural types, reactivity and properties of these compounds are summarized and systematized. Particular attention is paid to the redox, magnetic and catalytic properties and to biological activities of these complexes, which is important for understanding the areas of their potential application.
The bibliography includes 177 references.

Keywords: vanadium, niobium, tantalum, diimines, synthesis, crystal structure, reactivity, redox properties, magnetic properties, catalysts, biological activity.

Received: 13.02.2020

DOI: 10.1070/RCR4949


 English version:
Russian Chemical Reviews, 2020, 89:9, 966–998

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© Steklov Math. Inst. of RAS, 2024