M. N. Temnikov, I. N. Krizhanovskiy, A. A. Anisimov, S. P. Bedenko, K. I. Dementiev, I. V. Krylova, S. A. Milenin, A. L. Maksimov, M. P. Egorov, A. M. Muzafarov, “Direct synthesis of alkoxysilanes: current state, challenges and prospects”, Usp. Khim., 2023, Volume 92, Issue 7,Pages <nobr>1–30</nobr>

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Usp. Khim., 2023 Volume 92, Issue 7, Pages 1–30 (Mi rcr4429)

This article is cited in 3 papers

Direct synthesis of alkoxysilanes: current state, challenges and prospects

M. N. Temnikov^ab, I. N. Krizhanovskiy^ab, A. A. Anisimov^ab, S. P. Bedenko^cb, K. I. Dementiev^cb, I. V. Krylova^d, S. A. Milenin^ea, A. L. Maksimov^c, M. P. Egorov^d, A. M. Muzafarov^eb

^a L.N.Tolstoy Tula State Pedagogical University, Tula, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation
^c A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^d N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^e Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: This review analyzes the current state of the art in the direct synthesis ofalkoxysilanes (DSA). The main approaches, challenges and prospects of this process are highlighted. The plausible reaction mechanism is considered, as well as factors that have a significant influence on the process, including temperature, type and concentration of the catalyst, promoter additives, the method of carrying out the process, etc.
The bibliography includes 232 references.

Keywords: alkoxysilanes, organoalkoxysilanes, direct synthesis.

Received: 15.03.2023

DOI: 10.59761/RCR5081

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English version: Russian Chemical Reviews, 2023, 92:7, 1–28

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© Steklov Math. Inst. of RAS, 2024