S. G. Zlotin, K. S. Egorova, V. P. Ananikov, A. A. Akulov, M. V. Varaksin, O. N. Chupakhin, V. N. Charushin, K. P. Bryliakov, A. D. Averin, I. P. Beletskaya, E. L. Dolengovski, Yu. H. Budnikova, O. G. Sinyashin, Z. N. Gafurov, A. O. Kantyukov, D. G. Yakhvarov, A. V. Aksenov, M. N. Elinson, V. G. Nenajdenko, A. M. Chibiryaev, N. S. Nesterov, E. A. Kozlova, O. N. Mart'yanov, I. A. Balova, V. N. Sorokoumov, D. A. Guk, E. K. Beloglazkina, D. A. Lemenovskii, I. Yu. Chukicheva, L. L. Frolova, E. S. Izmest'ev, I. A. Dvornikova, A. V. Popov, A. V. Kutchin, D. M. Borisova, A. A. Kalinina, A. M. Muzafarov, I. V. Kuchurov, A. L. Maksimov, A. V. Zolotukhina, “The green chemistry paradigm in modern organic synthesis”, Usp. Khim., 2023, Volume 92, Issue 12,Pages <nobr>1–187</nobr>

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Usp. Khim., 2023 Volume 92, Issue 12, Pages 1–187 (Mi rcr4451)

This article is cited in 42 papers

The green chemistry paradigm in modern organic synthesis

S. G. Zlotin^a, K. S. Egorova^a, V. P. Ananikov^a, A. A. Akulov^b, M. V. Varaksin^cb, O. N. Chupakhin^cb, V. N. Charushin^cb, K. P. Bryliakov^a, A. D. Averin^d, I. P. Beletskaya^d, E. L. Dolengovski^e, Yu. H. Budnikova^e, O. G. Sinyashin^e, Z. N. Gafurov^e, A. O. Kantyukov^e, D. G. Yakhvarov^e, A. V. Aksenov^f, M. N. Elinson^a, V. G. Nenajdenko^d, A. M. Chibiryaev^g, N. S. Nesterov^g, E. A. Kozlova^g, O. N. Mart'yanov^g, I. A. Balova^h, V. N. Sorokoumov^h, D. A. Guk^d, E. K. Beloglazkina^d, D. A. Lemenovskii^d, I. Yu. Chukichevaⁱ, L. L. Frolovaⁱ, E. S. Izmest'evⁱ, I. A. Dvornikovaⁱ, A. V. Popovⁱ, A. V. Kutchinⁱ, D. M. Borisova^j, A. A. Kalinina^j, A. M. Muzafarov^jk, I. V. Kuchurov^a, A. L. Maksimov^l, A. V. Zolotukhina^l

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Ural Federal University named after the first President of Russia B.N.Yeltsin, Ekaterinburg, Russian Federation
^c Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
^d Department of Chemistry, Lomonosov Moscow State University, Moscow, Russian Federation
^e Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
^f North Caucasus Federal University, Stavropol
^g Federal Research Center Boreskov Institute of Catalysis, Novosibirsk, Russian Federation
^h Institute of Chemistry, Saint Petersburg State University, Saint Petersburg, Russian Federation
ⁱ Institute of Chemistry of Komi Science Center of Ural Branch of the Russian Academy of Sciences
^j Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation
^k A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation
^l A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: After the appearance of the green chemistry concept, which was introduced in the chemistry vocabulary in the early 1990s, its main statements have been continuously developed and modified. Currently, there are 10–12 cornerstones that should form the basis for an ideal chemical process. This review analyzes the accumulated experience and achievements towards the design of chemical products and processes that reduce or eliminate the use of generation of hazardous substances. The review presents the views of leading Russian professionals specializing in various fields of this subject, including homogeneous and heterogeneous catalysis, fine and basic organic synthesis, electrochemistry, polymer chemistry, chemistry based on bio-renewable feedstocks and chemistry of energetic compounds and materials. A new approach to the quantitative evaluation of the environmental friendliness of processes developed by Russian authors is described.
The bibliography includes 1761.

Keywords: green chemistry, C-H functionalisation, catalysis, cross-coupling, organocatalysis, electrochemistry, multicomponent reactions, cascade transformations, redox processes, deep eutectic solvents (DES), supercritical CO₂, biorenewable raw materials, polymers, emulsions, surfactants, energetic materials, industrial organic synthesis.

Received: 12.10.2023

DOI: 10.59761/RCR5104

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English version: Russian Chemical Reviews, 2023, 92:12, 1–187

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