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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2024 Volume 93, Issue 4, Pages 1–62 (Mi rcr4459)

This article is cited in 3 papers

Quantum dots: modern methods of synthesis and optical properties

A. A. Rempelab, O. V. Ovchinnikovc, I. A. Weinsteinab, S. V. Rempel'd, Yu. V. Kuznetsovad, A. V. Naumovefg, M. S. Smirnovc, I. Yu. Eremchevef, A. S. Vokhmintsevb, S. S. Savchenkob

a Institute of Metallurgy of the Ural Branch, Russian Academy of Science, Ekaterinburg, Russian Federation
b Ural Federal University, Ekaterinburg, Russian Federation
c Voronezh State University, Voronezh, Russia
d Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg, Russia
e Institute for Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow
f Moscow Pedagogical State University, Moscow, Russian Federation
g Troitsk Branch of the P.N.Lebedev Physical Institute of the Russian Academy of Sciences, Troitsk, Moscow, Russian Federation

Abstract: Quantum dots are the most exciting representatives of nanomaterials. They are synthesized by modern methods of nanotechnology pertaining to both inorganic and organic chemistry. Quantum dots possess unique physical and chemical properties; therefore, they are used in very different fields of physics, chemistry, biology, engineering and medicine. It is not surprising that the Nobel Prize in chemistry in 2023 was given for discovery and synthesis of quantum dots. In this review, modern methods of synthesis of quantum dots, their optical properties and practical applications are analyzed. In the beginning, a short historical background of quantum dots is given. Many gifted scientists, including chemists and physicists, were engaged in these studies. The synthesis of quantum dots in solid and liquid matrices is described in detail. Quantum dots are well-known owing to their unique optical properties, that is why the attention in the review is focused on the quantum-size effect. The causes for fascinating blinking of quantum dots and techniques for observation of a single quantum dot are explained. The last part of the review describes important applications of quantum dots in biology, medicine and quantum technologies.
Bibliography — 772 references.

Keywords: Quantum Dots, Size Effects, Excitons, Blueshift, Aqueous Synthesis, Optical spectroscopy, Blinking, Biolabels, Luminescence Nanothermometry, Memristors.

Received: 07.12.2023

DOI: 10.59761/RCR5114


 English version:
Russian Chemical Reviews, 2024, 93:4, 1–62


© Steklov Math. Inst. of RAS, 2024