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Usp. Khim., 2025 Volume 94, Issue 2, Pages 1–38 (Mi rcr4492)

Long-term durability of membrane electrode assemblies of proton exchange fuel cells: challenges and solutions

A. G. Kastsova, A. O. Krasnova, N. V. Glebova, A. O. Pelageikina, A. A. Nechitailov

Ioffe Institute, Russian Academy of Sciences, Saint Petersburg, Russian Federation

Abstract: The review addresses the problem of durability of operation of low-temperature proton exchange membrane fuel cells. Fuel cells are of considerable interest for the transition to renewable energy sources; however, the durability of these devices is still not sufficiently long (10 to 40 thousand hours). The increase in the durability is a relevant task. The review presents a systematic account and evaluation of the methods used for stabilization of electrochemical energy conversion systems with a proton exchange membrane and defines promising approaches to increase their lifetime.
The bibliography includes 197 references.

Keywords: fuel cell, water electrolyzer, degradation, long-term operation, membrane modification, ionomer stabilization, SMSI.

Received: 03.06.2024

DOI: 10.59761/RCR5135


 English version:
Russian Chemical Reviews, 2025, 94:2, 1–34

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© Steklov Math. Inst. of RAS, 2025