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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2004 Volume 73, Issue 11, Pages 1123–1130 (Mi rcr488)

This article is cited in 42 papers

Spin catalysis as a new type of catalysis in chemistry

A. L. Buchachenkoa, V. L. Berdinskyb

a N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region

Abstract: A new phenomenon, spin catalysis, i.e., stimulation of chemical reactions by removing the prohibitions imposed for reasons of electron angular momentum (spin) of reactants is considered. The physical and chemical mechanisms of this phenomenon are discussed. The nature of spin catalysts, the quantitative measure of catalytic effects and the types of chemical reactions susceptible to spin catalysis are considered.

Received: 16.12.2003

DOI: 10.1070/RC2004v073n11ABEH000888


 English version:
Russian Chemical Reviews, 2004, 73:11, 1033–1039

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