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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2012 Volume 81, Issue 10, Pages 936–959 (Mi rcr610)

This article is cited in 34 papers

Porous structure and wetting of fuel cell components as the factors determining their electrochemical characteristics

Yu. M. Volfkovich, V. E. Sosenkin

Frumkin Institute of Electrochemistry, Russian Academy of Sciences

Abstract: The results of studies of the principal components of the membrane-electrode assembly (ion-exchange and capillary membranes, polymer hydrophobization agents) obtained by standard contact porosimetry are considered. The phenomenon of inversion of ion-exchange groups of ionomers that affects the hydrophilic-hydrophobic properties of catalytic layers is described. The effect of the porous structure and wettability of components of the membrane-electrode assembly on the electrochemical characteristics of fuel cells is discussed. The bibliography includes 167 references.

Received: 01.11.2011

DOI: 10.1070/RC2012v081n10ABEH004281


 English version:
Russian Chemical Reviews, 2012, 81:10, 936–959

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