A. V. Shchepochkin, O. N. Chupakhin, V. N. Charushin, V. A. Petrosyan, “Direct nucleophilic functionalization of <nobr>$\mathrm{C(sp^2)-H}$</nobr> bonds in (hetero)arenes by electrochemical methods”, Usp. Khim., 2013, Volume 82, Issue 8,Pages <nobr>747

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Direct nucleophilic functionalization of $\mathrm{C(sp^2)-H}$ bonds in (hetero)arenes by electrochemical methods

A. V. Shchepochkin^a, O. N. Chupakhin^ab, V. N. Charushin^a, V. A. Petrosyan^c

^a I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Ekaterinburg
^b Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg
^c N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Abstract: Published data on electrochemical methods and approaches used for direct functionalization of the $\mathrm{C(sp^{2})-H}$ bond through nucleophilic displacement of hydrogen ($\mathrm{S_{N}^{H}}$-reactions) are surveyed and described systematically. The most important features of preparative electrochemical processes are considered. The attention is concentrated on the synthetic potential of the discussed transformations.
Bibliography 133 references.

Received: 19.03.2013

DOI: 10.1070/RC2013v082n08ABEH004386