Abstract:
The information that has appeared during the last 15 years relating to enantioselectivity in the formation and reactions of kinetically inert and kinetically labile complexes is classified in the present review. Attention is mainly given to chiral discrimination of ligands that are exchanged in the internal or external coordination spheres of the complexes. The occurrence of enantioselective effects has also been recorded in reactions of coordination compounds that occur without ligand exchange, in particular, in photochemical processes. The variety of forms in which enantioselectivity is displayed is shown and methods for studying it are described. The bibliography includes 223 references.