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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1990 Volume 59, Issue 12, Pages 2034–2057 (Mi rcr866)

This article is cited in 9 papers

Metal-complex catalysis of the polymerisation of α-olefins

B. A. Krentsel', L. A. Nekhaeva

A. V. Topchiev Institute of Petrochemical Synthesis of the Academy of Sciences of the USSR, Moscow

Abstract: The progress in the development and application of metal-complex catalysis in the polymerisation of α-olefins during the last ten years is reviewed and evaluated. The methods of modifying previously known catalytic systems are characterised and the experimental results of studies on novel types of catalysts, including Ti–Mg, metallocene, lanthanide, and ylide systems are reported. Some views about further improvement of the activity and stereospeciflcity of metal-complex catalysts in relation to the chemistry of polyolefins are stated.
The bibliography includes 242 references.

UDC: 541.64:547.313

DOI: 10.1070/RC1990v059n12ABEH003587


 English version:
Russian Chemical Reviews, 1990, 59:12, 1193–1207

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