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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1991 Volume 60, Issue 6, Pages 1190–1228 (Mi rcr936)

This article is cited in 12 papers

Oxidation of phosphine and arsine by metal complexes and free and bound oxygen

Ya. A. Dorfman, I. M. Yukht, L. V. Levina, G. S. Polimbetova, T. V. Petrova, V. S. Emel'yanova

Institute of Organic Catalysis and Electrochemistry of the Kazakh SSR, Alma-Ata

Abstract: Data on the oxidation of PH3 and AsH3 by metal complexes and oxygen compounds of metals and non-metals and on their catalytic and coupled oxidation by dioxygen, ozone, and peroxide compounds are analysed. The methods for the activation of oxidants, phosphine, and arsine, ensuring the acceleration of the oxidative reactions in processes involving the elimination of the extremely harmful impurities PH3 and AsH3 from gases, are examined. The bibliography includes 176 references.

UDC: 547+546+541

DOI: 10.1070/RC1991v060n06ABEH001097


 English version:
Russian Chemical Reviews, 1991, 60:6, 605–627

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