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JOURNALS // Zhurnal Srednevolzhskogo Matematicheskogo Obshchestva // Archive

Zhurnal SVMO, 2010, Volume 12, Number 3, Pages 55–58 (Mi svmo45)

In Middle Volga Mathematical Society

Discrination of kinetical equation type for reaction of benzene with ethylene alkilation

A. V. Balaev, N. M. Safuanova

Institute of Petrochemistry and Catalysis of RAS

Abstract: In this work are presented the results received under development of kinetic model of benzene with ethylene alkylation reaction on zeolite catalyst ZSM-5. It was carried out discrimination of kinetic equations and for further investigation was proposed to use Langmuir-Hinshelwood relations with surface reaction rate-determining step. It was solved inversed kinetic problem and were estimated kinetic parameters, which described experimental data in the limits of quantities analysis inaccuracy.

Keywords: Kinetic equations, system of differential equations, law action mass, Langmuir-Hinshelwood relations, reaction rate constants, activation energies, adsorption parameters.

UDC: 519.876.5

Received: 22.12.2010



© Steklov Math. Inst. of RAS, 2024