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JOURNALS // Teoreticheskaya i Matematicheskaya Fizika // Archive

TMF, 1996 Volume 108, Number 1, Pages 135–158 (Mi tmf1183)

This article is cited in 5 papers

Analytic representation for the equation of state in classical statistical mechanics

I. I. Ivanchik

P. N. Lebedev Physical Institute, Russian Academy of Sciences

Abstract: For the system of classical particles interacting by pair short-range forces the explicitly convergent expansions on usual and complementary density and the contour integral representations are constructed for the all-round compression modulus, the modulus being sufficient to describe all the thermodynamic properties and being tentatively single-valued in the vicinity of the phase transition point. With the help of those the analytic representations of the equation of state as well as specific configuration integral are found. The elaborated technique is approved on the exactly solved model – the theory of the Van der Waals substance being a model “substance” for which the Van der Waals equation is the exact equation of state.

Received: 06.07.1995

DOI: 10.4213/tmf1183


 English version:
Theoretical and Mathematical Physics, 1996, 108:1, 958–976

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