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TMF, 2003 Volume 134, Number 2, Pages 325–336 (Mi tmf153)

This article is cited in 6 papers

Thermodynamics and Hydrodynamics (Statistical Foundations): 2. Thermodynamic Equilibrium

G. A. Martynov

Institute of Physical Chemistry, Russian Academy of Sciences

Abstract: We show that the BBGKY hierarchy in thermodynamic equilibrium degenerates into an equilibrium hierarchy. In turn, the latter can be used to obtain both the fundamental system of equations describing the state of matter inside a correlation sphere of the radius $R\approx10^{-7}$cm and the canonical Gibbs distribution, which, according to the current concepts, describes the state of the entire macroscopic system. We show that the Gibbs distribution is indeed also local, i.e., describes the state of matter only inside the correlation sphere; in the thermostat surrounding this sphere, the Gibbs distribution degenerates into a constant. We state that these two approaches are equivalent to each other.

Keywords: equilibrium BBGKY hierarchy, local approach, Gibbs distribution, Ornstein–Zernike equation, correlation sphere, thermostat.

Received: 26.11.2001
Revised: 19.02.2002

DOI: 10.4213/tmf153


 English version:
Theoretical and Mathematical Physics, 2003, 134:2, 285–294

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