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TMF, 1977 Volume 32, Number 3, Pages 410–415 (Mi tmf3191)

Calculation of equilibrium mean values in a system of molecules interacting with a radiation field

V. V. Zverev


Abstract: Method of calculating the temperature averages of collective variables in the system of $N$ many-level moleculi interacting with radiation field is suggested. Decomposition of the space of states of the moleculi over the subspaces of irreducible representations of the group $U(n)$ is used. Calculations are performed in the basis of the coherent states of the unitary group, which are the quasiclassical states of the radiators in the limit $N\to\infty$. An unexpected statistical interpretation of some group-theoretical quantities is obtained. The method proposed for calculating the averages is used for determining the conditions of the phase transition into spontaneous coherent state.

Received: 30.11.1976


 English version:
Theoretical and Mathematical Physics, 1977, 32:3, 828–832


© Steklov Math. Inst. of RAS, 2024