Abstract:
Expressions are obtained in the quasiclassical approximation for the amplitudes of
excitation, dissociation, and exchange in the collinear collision of a diatomic
molecule and a structureless atom. For the atom-harmonic oscillator model the
numerically obtained excitation probabilities agree well with the exact quantum
values and are identical to the quasielassical results obtained by the "classical
$S$ matrix" method.