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TMF, 1989 Volume 81, Number 3, Pages 455–467 (Mi tmf5385)

Thermodynamic functions of a two-component spatially homogeneous system near the critical separation point

O. V. Patsahan, I. R. Yukhnovskii


Abstract: In the vicinity of critical separation point the evident expression for free energy of double component isotropic system as the function of composition, temperature and Hamiltonian initial parameters is received. With $T\geqslant T_c$ the investigated system represents homogeneous mixture. With $T\leqslant T_c$ the sphere of free energy instability according to concentration is determined in which the component stratification takes place. The expressions for entropy and specific heat are also given.

Received: 13.07.1988


 English version:
Theoretical and Mathematical Physics, 1989, 81:3, 1329–1338

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