RUS  ENG
Full version
JOURNALS // Teoreticheskaya i Matematicheskaya Fizika // Archive

TMF, 1991 Volume 88, Number 1, Pages 31–36 (Mi tmf5772)

This article is cited in 2 papers

Analytic properties of solution of electronic Schrödinger equation

P. V. Ganelin, V. I. Pupyshev


Abstract: It is shown that for a nondegenerate electronic state of a molecule the energy is an analytic function of the nuclear coordinates everywhere except points at which the nuclei coincide. The proof is based on construction of a parametric substitution of the coordinates and an associated analytic family of operators. It is found that the eigenfunctions of the molecular Hamiltonian do not have a square integrable third derivative with respect to the nuclear coordinates.

Received: 18.04.1990


 English version:
Theoretical and Mathematical Physics, 1991, 88:1, 694–698

Bibliographic databases:


© Steklov Math. Inst. of RAS, 2024