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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2019 Volume 57, Issue 2, Pages 198–202 (Mi tvt11094)

This article is cited in 2 papers

Thermophysical Properties of Materials

Heat capacity of nickel–phosphorus eutectic melts

L. V. Kamaeva, V. I. Lad'yanov

Udmurt Federal Research Center of the Ural Branch of the Russian Academy of Sciences, Izhevsk

Abstract: $\rm Ni$$\rm P$ alloys containing phosphorus from $15$ to $23$ at $\%$, which is close to the eutectic concentration, are studied with differential scanning calorimetry. The heat capacity $C_P$ is calculated at a constant pressure for the melts from the obtained data. The $C_P$ values of the alloys at temperatures above their melting points at $50^{\circ}$C are $0.53$$0.59$ J/(g K) and are in good agreement with the literature heat capacity values for liquid nickel and $\rm Ni_3\rm P$. The $C_P$ of all of the melts linearly increases from the $T_L$ liquidus temperature to $1400^{\circ}$Ñ. There is a maximum on the concentration dependence of $C_P$ at the eutectic concentration.

UDC: 536.632:546.74'18

Received: 19.07.2018
Accepted: 10.10.2018

DOI: 10.1134/S0040364419020066


 English version:
High Temperature, 2019, 57:2, 177–181

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