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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2022 Volume 60, Issue 1, Pages 46–50 (Mi tvt11519)

Thermophysical Properties of Materials

Thermodynamics of the evaporation of scandium trifluoride and the composition of its vapor

E. L. Osinaa, S. B. Osinb

a Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow
b Lomonosov Moscow State University, Faculty of Chemistry

Abstract: Based on the critical analysis of the experimental and theoretical data on the structure and vibrational frequencies of dimeric scandium trifluoride, the molecular constant values of the $\rm Sc_2\rm F_6$ compound are chosen and its thermodynamic functions are calculated. The scandium trifluoride vapor composition is calculated in the temperature range of $1200$ to $1825$ K. The enthalpies of sublimation and formation of the scandium trifluoride monomer and dimer are determined according to the third law of thermodynamics. The values obtained are added to the IVTANTHERMO software package database.

UDC: 544.31.031:546.881.5

Received: 24.12.2020
Revised: 31.05.2021
Accepted: 28.09.2021

DOI: 10.31857/S0040364422010215


 English version:
High Temperature, 2022, 60:1, 41–44

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© Steklov Math. Inst. of RAS, 2024