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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2022 Volume 60, Issue 1, Pages 23–32 (Mi tvt11531)

This article is cited in 1 paper

Thermophysical Properties of Materials

Thermodynamic properties of $\rm ZrC_{0.95-0.99}$ zirconium carbide in a condensed state

N. M. Aristovaa, G. V. Belovb

a Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow
b Lomonosov Moscow State University, Faculty of Chemistry

Abstract: Based on the specific heat equations obtained earlier for crystalline $(298.15$$3840$ K$)$ and liquid $(3840$$5000$ K$)$ zirconium carbide with composition close to stoichiometric, we calculated the thermodynamic functions for $\rm ZrC_{0.95-0.99}$ at temperatures of $100$ to $5000$ K. Special attention is paid to the nature of the anomalous growth of the enthalpy and the specific heat of the crystalline $\mathrm{ZrC}_x$ at temperatures above $\sim2200$ K. The calculated thermodynamic functions are included in the IVTANTHERMO database.

UDC: 546.261 + 536.63

Received: 03.02.2021
Revised: 03.02.2021
Accepted: 19.05.2021

DOI: 10.31857/S004036442201001X


 English version:
High Temperature, 2022, 60:1, 19–27

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© Steklov Math. Inst. of RAS, 2025