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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2022 Volume 60, Issue 4, Pages 629–632 (Mi tvt11677)

Short Communications

The binodal of sulfur and similarity laws for the line of the unit compressibility factor

E. M. Apfelbaum

Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow

Abstract: The article shows that the similarity laws in the region of a liquid and fluid for the line of the unit compressibility factor obtained earlier for substances with a constant composition are also applicable to such a substance as sulfur. In the vicinity of its critical point two- to three-atom clusters predominate, while in the vicinity of sulfure melting line, eight-atom clusters predominate. The liquid–gas binodal, constructed on the basis of these similarity laws, agrees well with the known experimental data.

UDC: 536.71

Received: 02.12.2021
Revised: 02.03.2022
Accepted: 07.06.2022

DOI: 10.31857/S0040364422040184


 English version:
High Temperature, 2022, 60:4, 574–577

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© Steklov Math. Inst. of RAS, 2024