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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2005 Volume 43, Issue 5, Pages 727–731 (Mi tvt1421)

This article is cited in 1 paper

Thermophysical Properties of Materials

The Heat Capacity and Thermodynamic Functions of Ternary Manganites $\text{DyM}^{\text{I}}\text{MgMn}_2\text{O}_6$ $(\text{M}^{\text{I}}$ - $\text{Na}$, $\text{K}$, $\text{Cs})$ in the Temperature Range from $223$ to $673$ K

B. K. Kasenov, Zh. N. Akisheva, E. S. Mustafin, Sh. B. Kasenova, Zh. I. Sagintaeva, Zh. S. Bekturganov, M. A. Akubaeva

Institute for Phytochemistry, Ministry of Education and Science, Republic of Kazakhstan, Karaganda

Abstract: The solid-phase method is used to synthesize ternary manganites of composition $\text{DyM}^{\text{I}}\text{MgMn}_2\text{O}_6$ $(\text{M}^{\text{I}}$ - $\text{Na}$, $\text{K}$, $\text{Cs})$; their X-ray investigation is performed to demonstrate that they all crystallize in orthorhombic system. Their heat capacity is determined experimentally in the range from $223$ to $673$ K, equations are derived which describe the dependences $C^{\circ}_p \sim f(T)$, and the thermodynamic functions $C^{\circ}_p(T)$, $H^{\circ}(T) - H^{\circ}(298.15)$, $S^{\circ}(T)$, and $\Phi^{**}(T)$ are calculated. Second-order phase transitions are observed in the process of investigation of heat capacity.

UDC: 536.6+66-971+546.711/717

Received: 02.09.2004


 English version:
High Temperature, 2005, 43:5, 727–732


© Steklov Math. Inst. of RAS, 2024