RUS  ENG
Full version
JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2004 Volume 42, Issue 6, Pages 878–884 (Mi tvt1604)

This article is cited in 3 papers

Thermophysical Properties of Materials

Interaction potentials of nine quasi-spherical molecules in the database on the transport properties of gases

L. R. Fokina, L. Zarkovab, M. Damyanovab

a Institute for High Temperatures, Russian Academy of Sciences, Moscow
b Institute of Electronics, Bulgarian Academy of Sciences, Sofia, Bulgaria

Abstract: Experimental data on the second virial coefficient and viscosity are generalized using ($m-6$) Lennard-Jones potentials with four and three parameters for a group of rarefied gases consisting of quasi-spherical molecules with tetra- and octahedral symmetry. Analysis is made of correlations of the parameters of potentials with the structural characteristics of molecules and critical temperatures of substances. The parameters of three-parameter ($m-6$) Lennard–Jones potential for nine molecules of $\mathrm{CH}_4$, $\mathrm{CF}_4$, $\mathrm{CCl}_4$, $\mathrm{C}(\mathrm{CH}_3)_4$, $\mathrm{SiCl}_4$, $\mathrm{Si}(\mathrm{CH}_3)_4$, $\mathrm{SF}_6$, $\mathrm{MoF}_6$, and $\mathrm{WF}_6$ are included in the EPIDIF information-and-computation database (epitaxy and diffusion processes) on the transport properties of rarefied gases and gas mixtures.

UDC: 536.681

Received: 17.03.2004


 English version:
High Temperature, 2004, 42:6, 888–894


© Steklov Math. Inst. of RAS, 2025