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Plasma Investigations
Inelastic interaction of an electron with a $\mathrm{C}_{60}$ cluster
A. A. Vostrikov,
D. Yu. Dubov,
A. A. Agarkov Institute of Thermophysics, Siberian Division of the Russian Academy of Sciences, Novosibirsk
Abstract:
The method of intersecting beams of
$\mathrm{C}_{60}$ fullerene clusters and of electrons is used to investigate the production of
$\mathrm{C}_{60}^+$ and
$\mathrm{C}_{60}^-$ ions and the radiation in the wavelength range from
$300$ to
$800$ nm for the electron energy
$E_e$ ranging from zero to
$100$ eV. The absolute values of the ionization and electron-attachment cross sections [
$\sigma^+(E_e )$ and
$\sigma^-(E_e)$, respectively] are determined. A maximum of
$\sigma^+(E_e)$ of 0.53 nm
$^2$ is observed at
$E_e=52$ eV. For a
$\mathrm{C}_{60}$ cluster excited by electron impact, "delayed" (
$\sim150 \mu$s) ionization initiated by collision with the surface and ionization due to thermionic emission (its characteristic time at
$E_e=60$ eV is
$6\mu$s) is observed. It is found that, for
$E_e < 0.4$ eV, the formation of
$\mathrm{C}_{60}^-$ is defined by the polarization capture of an
$s$-electron (
$\sigma^-\sim E^{-1}_e$), and a formula is suggested for determining
$\sigma^-(E_e)$. In the region of
$E_e$ from
$1$ to
$6$ eV, the cross section
$\sigma^-(E_e)$ shows only slight variations about
$\sigma^-(E_e)=0.36\pm 0.03$ nm
$^2$. For
$E_e>7.5$ eV,
$\mathrm{C}_{60}^-$ ions proved to be unstable to electron autodetachment. In the region of intersection of
$\mathrm{C}_{60}$ and electron beams, radiation of a quasicontinuous spectrum described by a modified Planck formula for the thermal emission of spherical particles of diameter
$d\ll\lambda$ is recorded. For
$E_e>47$ eV, the brightness temperature proved to be
$3150\pm50$ K. It is found that this radiation is emitted predominantly by hot
$\mathrm{C}_{60}^{+*}$ ions produced as a result of thermionic emission from
$\mathrm{C}_{60}^*$. The rate of radiation loss of energy by a
$\mathrm{C}_{60}^{+*}$ ion and the cross section for the formation of radiating
$\mathrm{C}_{60}^{+*}$ ions are found to be, respectively,
$5.5\times 105$ eV/s at
$T=3150$ K and
$2\times10^{-2}$ nm
$^2$ at
$E_e=60$ eV.
UDC:
539.19.541.5
Received: 23.02.2000