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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2016 Volume 54, Issue 5, Pages 821–824 (Mi tvt2026)

This article is cited in 2 papers

Short Communications

Dissociation energy of a $\rm Sc_2$ molecule

A. V. Gusarov

Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow

Abstract: The $-(G^{\circ}(T) - H^{\circ}(0))/T$ Gibbs energy functions have been calculated for $\rm Sc_2$ at $T = 2000$ K in the context of recent data on the low-lying electron states for this kind of molecules. In particular, some recent experimental results on the vapor composition over scandium are presented in this study. The data on the measured scandium vapor composition have been processed using the evaluated Gibbs energy function values. The advised dissociation energy value for $\rm Sc_2$ is found to be $(\rm Sc_2) = 7750 \pm 1750$ cm$^{–1}$.

UDC: 536.7+541.11

Received: 29.04.2016

DOI: 10.7868/S0040364416050112


 English version:
High Temperature, 2016, 54:5, 771–774

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© Steklov Math. Inst. of RAS, 2024