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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2017 Volume 55, Issue 2, Pages 233–239 (Mi tvt4949)

Thermophysical Properties of Materials

Rankinite synthesis and pyrolysis inversion

V. S. Engel'shta, V. Zh. Muratalievab

a Institute of Physical-Technical Problems and Material Sciences, NAS of Kirgiz Republic, Bishkek
b Kyrgyz State Technical University named after Iskhak Razzakov

Abstract: The thermal transformation of the pyrolysis–condensation–rankinite synthesis process at a normal pressure is considered in detail. Rankinite pyrolysis is performed with a step-by-step increase in enthalpy (TERRA software system). Rankinite pyrolysis compounds are condensed on a surface with temperature $T = 298.15$ K. Condensate compounds are equivalent to pyrolysis compounds. Wollastonite and limestone can precipitate upon condensation to form a mineral deposit. Synthesis is performed by mixing the condensate compounds. The compounds and heat of chemical reactions, the enthalpy, the temperature, and the heat content have been determined. It has been shown that the decomposition of rankinite $(T_{\rm dec} = 2598.36$ K$)$, wollastonite $(T_{\rm dec} = 3662.7$ K$)$, and limestone $(T_{\rm dec} = 3680$$3810$ K$)$ occurs in the process of synthesis and pyrolysis at a constant temperature. The complete pyrolysis–condensation–synthesis process picture typical for various compounds is given.

UDC: 536.7:662.74

Received: 05.07.2015
Accepted: 22.12.2015

DOI: 10.7868/S0040364417010082


 English version:
High Temperature, 2017, 55:2, 226–232

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