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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2013 Volume 51, Issue 1, Pages 79–85 (Mi tvt59)

This article is cited in 24 papers

Thermophysical Properties of Materials

Asymptotic properties of ideal curves on a thermodynamic surface

V. I. Nedostup

Physico-Chemical Institute, National Academy of Science of Ukraine, Odessa, Ukraine

Abstract: The configurations and properties of the characteristic curves on the thermodynamic surface of a real gas, that is, of locus points where the configuration component of a thermodynamic property becomes zero, have been analyzed. The relation of asymptotic properties of the curves with a virial equation of state at $\rho\to0$ and with a hypothetical fluid system overcooled to $0$ K at $T\to0$ has been studied. The correlation of asymptotic properties of the curves manifesting themselves, in particular, in the direct relationship of coordinates of characteristic points of ideal curves on a thermodynamic surface with an intermolecular interaction potential has been demonstrated.

UDC: 543.27

Received: 13.12.2011


 English version:
High Temperature, 2013, 51:1, 72–78

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