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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2011 Volume 49, Issue 6, Pages 887–892 (Mi tvt597)

This article is cited in 1 paper

Thermophysical Properties of Materials

Activity Coefficients and Other Thermodynamic Characteristics of $\mathrm{Li}$$\mathrm{LiH}$ ($\mathrm{LiD}$, $\mathrm{LiT}$) Binary Solutions at Liquid–Vapor Phase Equilibrium

K. A. Yakimovich, A. G. Mozgovoi

Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow

Abstract: A $\mathrm{Li}$$\mathrm{LiH}$–type system at liquid–vapor phase equilibrium is considered. The experimental data on vapor pressure is processed, and the approximate equations for the temperature dependence of the equilibrium constant, activity coefficients, and other thermodynamic characteristics are found. The presence of an analog of the Sieverts constant in the region of liquid hydride concentrations in solution at $x \approx 1$ is found for the first time. Previously unknown dependences for the $\mathrm{Li}$$\mathrm{LiT}$ system are obtained.

UDC: 536.7; 541.44

Received: 09.11.2010


 English version:
High Temperature, 2011, 49:6, 856–861

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