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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2009 Volume 47, Issue 1, Pages 31–36 (Mi tvt658)

Thermophysical Properties of Materials

The calorimetry and thermodynamic functions of $\mathrm{NdMe}^{\mathrm{I}}_3\mathrm{Mg}_3\mathrm{Mn}_4\mathrm{O}_{12}$ $(\mathrm{Me}^{\mathrm{I}} - \mathrm{Li, Na, K})$ manganites in the range from $298.15$ to $673$ K

B. K. Kasenov, E. S. Mustafin, Sh. B. Kasenova, Zh. I. Sagintaeva, S. T. Edil'baeva, S. Zh. Davrenbekov

JSC International Research and Production Holding "PhytoChemistry"

Abstract: The ceramic technology is employed for synthesizing manganites of composition $\mathrm{NdMe}^{\mathrm{I}}_3\mathrm{Mg}_3\mathrm{Mn}_4\mathrm{O}_{12}$ $(\mathrm{Me}^{\mathrm{I}} - \mathrm{Li, Na, K})$. The X-ray technique is used to find that the compounds crystallize in tetragonal syngony. The parameters of their crystal lattices are determined. Their heat capacities are experimentally determined in the range from $298.15$ to $673$ K, which enables one to reveal second-order phase transitions. In view of these transitions, equations describing the $C^{\circ}_p \sim f(T)$ dependence are derived, and the thermodynamic functions $C^{\circ}_p(T)$, $H^{\circ}(T) - H^{\circ}(298.15)$, $S^{\circ}(T)$ è $\Phi^{xx}(T)$ are calculated.

UDC: 546.65+536.6;7+546.711/717

PACS: 65.40.Ba, 65.40.Gr

Received: 23.07.2007


 English version:
High Temperature, 2009, 47:1, 27–32

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© Steklov Math. Inst. of RAS, 2025