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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2009 Volume 47, Issue 3, Pages 360–370 (Mi tvt815)

This article is cited in 6 papers

Thermophysical Properties of Materials

The absorption of carbon and nitrogen monoxides by ultradisperse aqueous system: Computer experiment

A. E. Galashev, O. R. Rakhmanova, V. N. Tchukanov

Institute of Industrial Ecology Ural Branch of RAS, Ekaterinburg

Abstract: The method of molecular dynamics is used to investigate the effect of absorption of carbon and nitrogen monoxides on the spectral characteristics of a disperse aqueous system. The absorption of $\text{CO}$ molecules causes the reduction of the real and imaginary parts of permittivity, and the absorption of $\text{NO}$ molecules results in smoothing out of the frequency dependence of these characteristics, which corresponds to that of a system of clusters of pure water. The integral absorptance and reflectance of IR radiation decrease after the attachment of $\text{CO}$ molecules to water clusters and undergo insignificant changes as a result of absorption of $\text{NO}$ molecules. An increase is observed in the integral power of emission of infrared radiation by disperse aqueous systems which absorbed $\text{CO}$ or $\text{NO}$ molecules. The clustering of water vapor causes an abrupt reduction of the number of scattering centers and the anti-greenhouse effect.

UDC: 535.34:535.233

PACS: 33.20 Ea; 36.40. Vz

Received: 15.04.2008


 English version:
High Temperature, 2009, 47:3, 342–351

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