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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2009 Volume 47, Issue 6, Pages 835–849 (Mi tvt939)

This article is cited in 5 papers

Thermophysical Properties of Materials

Equilibrium constants of interaction between zirconia and oxygen

E. P. Pakhomov

Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow

Abstract: The values of all ten equilibrium constants of interaction between zirconia and oxygen of ambient medium and, accordingly, quantitative dependences of the number of crystal lattice defects on temperature and on partial oxygen pressure are found in view of the defect structure of $\text{ZrO}_{2 - x}$ suggested in [1] and of available experimental data on the nonstoichiometry $x$ and other properties of $\alpha$, $\beta$, and $\gamma$ modifications of $\text{ZrO}_{2 - x}$; the position of $x = 0$ boundaries is determined.

UDC: 544.022.347:546.831

Received: 06.05.2008


 English version:
High Temperature, 2009, 47:6, 801–814

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